GCSE_Chemistry_SpecPoint

4:12 know the possible products of complete and incomplete combustion of hydrocarbons with oxygen in the air

Complete Combustion happens when there is enough oxygen available, producing carbon dioxide (CO2) and water (H2O)

 

Incomplete Combustion happens when there is not enough oxygen available, with possible products being carbon monoxide (CO), carbon (C, soot), carbon dioxide (CO2) and water (H2O)

4:13 understand why carbon monoxide is poisonous, in terms of its effect on the capacity of blood to transport oxygen references to haemoglobin are not required

Carbon monoxide may be produced from the incomplete combustion of fuels:

Carbon monoxide is poisonous because it reduces the capacity of the blood to carry oxygen.

4:14 know that, in car engines, the temperature reached is high enough to allow nitrogen and oxygen from air to react, forming oxides of nitrogen

When fuels are burned in vehicle engines, high temperatures are reached.

At these high temperatures nitrogen and oxygen from the air react to produce nitrogen oxides:

          nitrogen          +          oxygen        →          nitrogen oxides

eg

          N2 (g)              +          O2 (g)          →          2NO (g)

In the atmosphere these nitrogen oxides can combine with water to produce nitric acid (HNO3).

4:15 explain how the combustion of some impurities in hydrocarbon fuels results in the formation of sulfur dioxide

Fossil fuels such as coal, gas and oil are derived from crude oil.

These fuels are hydrocarbons, but also include impurities such as sulfur.

When the fuels are burned, sulfur dioxide is produced which can escape into the atmosphere:

S (s)         +         O₂ (g)         →         SO₂ (g)

 

4:16 understand how sulfur dioxide and oxides of nitrogen oxides contribute to acid rain

Acids formed in the atmosphere can fall as acid rain. This can be a major problem, killing trees and fish in lakes. The acid rain also corrodes limestone buildings and marble statues since these are both made of calcium carbonate (CaCO₃). Some metals such as iron are also attacked by acid rain.

 

Sulfur dioxide released into the atmosphere from the burning of fossil fuels can react with water and oxygen to make sulfuric acid (H₂SO₄):

2SO₂ (g)         +         2H₂O (l)         +         O₂ (g)         →         2H₂SO₄ (aq)

 

Also, if sulfur dioxide in the atmosphere reacts with just water, a weaker acid called sulfurous acid (H₂SO₃) is formed:

SO₂ (g)         +         H₂O (l)         →         H₂SO₃ (aq)

 

In car engines the temperature is high enough for the nitrogen in the air to react with oxygen to produce oxides of nitrogen, e.g:

N₂ (g)         +         O₂ (g)         →         NO₂ (g)

In the atmosphere these nitrogen oxides can produce nitric acid (HNO₃).

4:17 describe how long-chain alkanes are converted to alkenes and shorter-chain alkanes by catalytic cracking (using silica or alumina as the catalyst and a temperature in the range of 600–700⁰C)

Cracking involves the thermal decomposition of long-chain alkanes into shorter-chain alkanes and alkenes:

Conditions

Temperature: 600oC

Catalyst: aluminium oxide, Al2O3

4:18 explain why cracking is necessary, in terms of the balance between supply and demand for different fractions

Cracking converts long chain hydrocarbons into short chain hydrocarbons.

Long-chain alkanes are broken down into alkanes and alkenes of shorter length.

Crude oil contains a surplus long chains.

Shorter chain hydrocarbons are in greater demand, e.g. petrol.

Cracking also produces alkenes which are used in making polymers and ethanol.

4:20 explain why alkanes are classified as saturated hydrocarbons

 

Saturated:   A molecule containing only single bonds between carbon atoms. For example, alkanes as described as saturated molecules.

Unsaturated:   A molecule containing a carbon-carbon double or triple bond. For example, alkenes as described as unsaturated molecules.

 

4:21 understand how to draw the structural and displayed formulae for alkanes with up to five carbon atoms in the molecule, and to name the unbranched-chain isomers

The displayed formulae show all the atoms and bonds drawn out.

The molecular formulae just show the number of each type of atom in the molecule.

4:22 describe the reactions of alkanes with halogens in the presence of ultraviolet radiation, limited to mono-substitution knowledge of reaction mechanisms is not required

Alkanes react with bromine in the presence of UV light, e.g. sunlight.

A hydrogen atom in the alkane is replaced by a bromine atom.

This is known as substitution.

 

4:23 know that alkenes contain the functional group >C=C<

Alkenes are a homologous series of hydrocarbons which contain a carbon-carbon double bond. This double bond is shown in formulae as a double line.

The names of alkenes end with “ene”.

An example is ethene, the structural formula for which is CH₂ = CH₂

For a molecule with more than two carbon atoms, the position of the double bond within the molecule can vary as indicated by the name and the structural formula.

4:25 explain why alkenes are classified as unsaturated hydrocarbons

Saturated:   A molecule containing only single bonds between carbon atoms. For example, alkanes as described as saturated molecules.

Unsaturated:   A molecule containing a carbon-carbon double or triple bond. For example, alkenes as described as unsaturated molecules.

4:26 understand how to draw the structural and displayed formulae for alkenes with up to four carbon atoms in the molecule, and name the unbranched-chain isomers. Knowledge of cis/trans or E/Z notation is not required

The displayed formulae show all the atoms and bonds drawn out.

The molecular formulae just show the number of each type of atom in the molecule.

4:27 describe the reactions of alkenes with bromine, to produce dibromoalkanes

Alkenes react with bromine water. UV light is not required for this reaction.

The double bond is broken and the bromine atoms are added. This is an addition reaction.

During this reaction there is a colour change from orange to colourless.

For example:

This is how we can test for the presence of an alkene or another type of unsaturated molecule.

 

 

4:28 describe how bromine water can be used to distinguish between an alkane and an alkene

In the absence of UV light an alkane added to bromine water will not react: the bromine water will stay orange.

However, alkenes react with bromine water even without UV light. There will be a colour change of orange to colourless.

 

 

 

4:29 (Triple only) know that alcohols contain the functional group −OH

The member of the homologous series called Alcohols have names which end in “ol”. Examples are methanol, ethanol and propanol.

Alcohols all contain an -OH functional group attached to a hydrocarbon chain.

4:30 (Triple only) understand how to draw structural and displayed formulae for methanol, ethanol, propanol (propan-1-ol only) and butanol (butan-1-ol only), and name each compound, the names propanol and butanol are acceptable

Structural formula and displayed formula for methanol:

CH₃-OH

 

Structural formula and displayed formula for ethanol:

CH₃-CH₂-OH                    (or simply C₂H₅OH)

Image result for ethanol

 

Structural formula and displayed formula for propan-1-ol:

CH₃-CH₂-CH₂-OH

 

Structural formula and displayed formula for butan-1-ol:

CH₃-CH₂-CH₂-CH₂-OH

 

4:31 (Triple only) know that ethanol can be oxidised by: burning in air or oxygen (complete combustion), reaction with oxygen in the air to form ethanoic acid (microbial oxidation), heating with potassium dichromate(VI) in dilute sulfuric acid to form ethanoic acid

1) Ethanol can be oxidised by complete combustion. With excess oxygen the complete combustion of ethanol (C₂H₅OH) in air produces carbon dioxide and water:

C₂H₅OH (l)         +         3O₂ (g)         →         2CO₂ (g)         +         3H₂O (l)

 

2) Ethanol can be oxidised in air in the presence of microorganisms (‘microbial oxidation’) to form ethanoic acid (CH₃COOH).

 

3) Ethanol can be oxidised by heating with the oxidising agent potassium dichromate(VI) (K₂Cr₂O₇) in dilute sulfuric acid (H₂SO₄).

In the equation below, [O] means oxygen from an oxidising agent.

CH₃CH₂OH         +         2[O]         →         CH₃COOH         +         H₂O

This mixture starts orange but when the reaction happens turns green which indicates the presence of Cr³⁺ ions which are formed when the potassium dichromate(VI) is reduced.

4:32 (Triple only) know that ethanol can be manufactured by: 1) reacting ethene with steam in the presence of a phosphoric acid catalyst at a temperature of about 300⁰C and a pressure of about 60–70atm; and 2) the fermentation of glucose, in the absence of air, at an optimum temperature of about 30⁰C and using the enzymes in yeast

In the hydration of ethene, ethanol is made by passing ethene and steam over a catalyst.

Water is added to ethene, this is known as hydration.

Conditions

Catalyst: Phosphoric acid (H3PO4)

Temperature: 300°C

Pressure: 60 atm

 

 

Fermentation is the conversion of sugar, e.g. glucose into ethanol by enzymes from yeast.

 

Conditions

Catalyst: Zymase (enzyme found in yeast)

Temperature: 30°C  –  The process is carried out at low temperatures as not to denature the enzymes.

Other: Anaerobic (no oxygen present) – if oxygen were present, the yeast produce carbon dioxide and water instead of ethanol.

 

4:33 (Triple only) understand the reasons for fermentation, in the absence of air, and at an optimum temperature

In the production of ethanol the process of fermentation is carried out at a low temperature (30⁰-40⁰).

Above 40⁰ the enzymes would permanently lose their structure (denature).

At a temperature lower than 30⁰ the process would be too slow.

 

Fermentation is conducted in the absence of air. In the presence of air (aerobic conditions), enzymes in the yeast produce carbon dioxide and water instead of ethanol.

Also, in the presence of air, the ethanol can oxidise to ethanoic acid.

 

4:35 (Triple only) understand how to draw structural and displayed formulae for unbranched- chain carboxylic acids with up to four carbon atoms in the molecule, and name each compound

The four simplest carboxylic acids are methanoic acid, ethanoic acid, propanoic acid and butanoic acid.

 

Methanoic acid

Displayed formula:Image result for methanoic acid

Molecular formula: CH₂O₂

Structural formula: HCOOH

 

Ethanoic acid

Displayed formula:

Molecular formula: C₂H₄O₂

Structural formula: CH₃COOH

 

Propanoic acid

Displayed formula:Image result for propanoic acid

Molecular formula: C₃H₆O₂

Structural formula: CH₃CH₂COOH

 

Butanoic acid

Displayed formula:Image result for butanoic acid

Molecular formula: C₄H₈O₂

Structural formula: CH₃CH₂CH₂COOH

4:36 (Triple only) describe the reactions of aqueous solutions of carboxylic acids with metals and metal carbonates

Dilute carboxylic acids react with metals in the same way as other dilute acids (e.g. hydrochloric acid) only more slowly.

For example, dilute ethanoic acid reacts with magnesium with a lot of fizzing to produce a salt and hydrogen, leaving a colourless solution of magnesium ethanoate:

magnesium      +      ethanoic acid      →      magnesium ethanoate      +      hydrogen

Mg (s)         +         2CH₃COOH (aq)         →         (CH₃COO)₂Mg (aq)         +         H₂ (g)

 

Dilute carboxylic acids react with metal carbonates as they do with other acids, to give a salt, carbon dioxide and water.

For example, dilute ethanoic acid reacts with sodium carbonate with a lot of fizzing to produce a salt,  carbon dioxide and water, leaving a colourless solution of sodium ethanoate:

sodium carbonate      +      ethanoic acid      →      sodium ethanoate      +      carbon dioxide      +      water

Na₂CO₃ (s)         +         2CH₃COOH (aq)         →         2CH₃COONa (aq)         +         CO₂ (g)         +         H₂O (l)

 

As can be seen in the examples above the charge on the ethanoate ion is -1.

 

4:39 (Triple only) know that ethyl ethanoate is the ester produced when ethanol and ethanoic acid react in the presence of an acid catalyst

Ethyl ethanoate is the ester produced when ethanol and ethanoic acid react in the presence of an acid catalyst.

ethanoic acid           +           ethanol           ⇋           ethyl ethanoate           +           water

CH₃COOH (l)         +         CH₃CH₂OH (l)         ⇋         CH₃COOCH₂CH₃ (l)         +         H₂O (l)

The ethyl ethanoate produced is an ester.

The reaction is called esterification.

The reaction can also be described as a condensation reaction because water is made when two molecules join together.

4:41 (Triple only) understand how to write the structural and displayed formulae of an ester, given the name or formula of the alcohol and carboxylic acid from which it is formed and vice versa

To work out the structure of the ester formed when an alcohol reacts with a carboxylic acid, it is easiest to first draw the structures of alcohol and acid and then remove the H₂O to see what is left when the molecules join.

For example, propan-1-ol and ethanoic acid react together to form propyl ethanoate and water.

         propan-1-ol            +            ethanoic acid            →            propyl ethanoate            +            water

         CH₃CH₂CH₂OH (l)         +         CH₃COOH (l)         →         CH₃COOCH₂CH₂CH₃ (l)          +         H₂O (l)

 

The displayed formula for esters is typically written to show the part which came from the carboxylic acid on the left:

This is still called propyl ethanoate: the alcohol bit of the name (propyl) comes first and then the carboxylic acid bit (ethanoate), even though the displayed formula is typically written the other way around. Notice that the structural formulae for esters is also typically written with the carboxylic acid bit first, so propyl ethanoate is CH₃COOCH₂CH₂CH₃.

4:42 (Triple only) know that esters are volatile compounds with distinctive smells and are used as food flavourings and in perfumes

Esters are volatile compounds with distinctive smells. A volatile liquid is one that turns into to a vapour easily.

Esters are used as food flavourings and in perfumes.

Esters are often described as having a sweet, fruity smell. They typically smell of bananas, raspberries, pears or other fruit because esters occur in all these natural products.

4:43 (Triple only) practical: prepare a sample of an ester such as ethyl ethanoate

Heating a mixture of ethanoic acid and ethanol produces a liquid called ethyl ethanoate. A few drops of concentrated sulfuric acid must be added for the reaction to work. The sulfuric acid acts as a catalyst.

ethanoic acid           +           ethanol           ⇋           ethyl ethanoate           +           water

CH₃COOH (l)         +         CH₃CH₂OH (l)         ⇋         CH₃COOCH₂CH₃ (l)         +         H₂O (l)

The ethyl ethanoate produced is an ester.

The reaction is called esterification.

The reaction can also be described as a condensation reaction because water is made when two molecules join together.

Notice that the reaction is reversible. Pure reactants are used to maximise the yield of ethyl ethanoate. Pure ethanoic acid is called glacial ethanoic acid.

4:44 know that an addition polymer is formed by joining up many small molecules called monomers

One bond in the double bond breaks.

Monomers join together to form a long chain.

Polymer contains only single bonds.

4:45 understand how to draw the repeat unit of an addition polymer, including poly(ethene), poly(propene), poly(chloroethene) and (poly)tetrafluroethene

                              

 

 

                              

 

 

                              

 

 

                              

4:46 understand how to deduce the structure of a monomer from the repeat unit of an addition polymer and vice versa

To deduce the structure of the monomer from a repeat unit:

  1. Remove the extending single bonds
  2. Draw in a double bond

 

 

 

Here’s a more complicated example, going from the polymer to the structure of the monomer

4:47 explain problems in the disposal of addition polymers, including: their inertness and inability to biodegrade, the production of toxic gases when they are burned

Polymers are inert (unreactive) as they have strong C-C bonds.

This makes them non-biodegradeable.

Biodegradable: the breakdown of a substance by microorganisms.

if burnt the addition polymers could produce toxic gases such as carbon monoxide and hydrogen chloride.

4:48 (Triple only) know that condensation polymerisation, in which a dicarboxylic acid reacts with a diol, produces a polyester and water

Condensation polymers are formed by a condensation reaction.

These polymers are formed by the combination of two different monomers, such as a dicarboxylic acid and a diol.

When these particular monomers join in an alternating pattern they form a long polymer called a polyester. Where each monomer joins to the next, a separate molecule of water is also produced.

 

 

4:49 (Triple only) Understand how to write the structural and displayed formula of a polyester, showing the repeat unit, given the formulae of the monomers from which it is formed, including the reaction of ethanedioic acid and ethanediol:

Polyesters are polymers formed when two types of monomer join together alternately. Where each joins to the next a small molecule, such as water or hydrogen chloride, is lost. This is called a condensation polymerisation reaction.

 

One of the monomers is a diol, an alcohol with a -OH functional group at each end. An example is hexane-1,6-diol which has the structural formula CH₂OHCH₂CH₂CH₂CH₂CH₂OH and the displayed formula:

Since it is only the -OH functional groups which are important for polymerisation, this can we re-written with the central block of carbons represented as a block:

 

The other monomer is a dicarboxylic acid, a molecule with a -COOH functional group at each end. An example is hexane-1,6-dioic acid which has the structural formula HOOCCH₂CH₂CH₂CH₂COOH and the displayed formula:

Since it is only the -COOH functional groups which are important for polymerisation, this can we re-written with the central block of 4 carbons represented as a block:

 

These two different types of monomer (the diol and the dicarboxylic acid) can join to form a polymer with the loss of a water molecule at every bond. As above, this can be simplified by only looking at the functional groups and representing the other carbons as blocks, so the whole process looks like:

 

A simple example of this is the condensation polymerisation reaction between ethanedioic acid and ethandiol:

4:50 (Triple only) know that some polyesters, known as biopolyesters, are biodegradable

There are environmental issues with the disposal of condensation polymers, though because of their ester linkage the issues are not as severe as with addition polymers. Normally condensation polymers can take hundreds of years to break down, but chemists has developed biopolyesters which break down much more quickly.

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Section 1: Principles of chemistry

      a) States of matter

      b) Atoms

      c) Atomic structure

     d) Relative formula masses and molar volumes of gases

     e) Chemical formulae and chemical equations

     f) Ionic compounds

     g) Covalent substances

     h) Metallic crystals

     i) Electrolysis

 Section 2: Chemistry of the elements

     a) The Periodic Table

     b) Group 1 elements: lithium, sodium and potassium

     c) Group 7 elements: chlorine, bromine and iodine

     d) Oxygen and oxides

     e) Hydrogen and water

     f) Reactivity series

     g) Tests for ions and gases

Section 3: Organic chemistry

     a) Introduction

     b) Alkanes

     c) Alkenes

     d) Ethanol

Section 4: Physical chemistry

     a) Acids, alkalis and salts

     b) Energetics

     c) Rates of reaction

     d) Equilibria

Section 5: Chemistry in industry

     a) Extraction and uses of metals

     b) Crude oil

     c) Synthetic polymers

     d) The industrial manufacture of chemicals

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